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81.
82.
Anja SZYMANSKI Frank E. BRENKER Herbert PALME Ahmed EL GORESY 《Meteoritics & planetary science》2010,45(1):21-31
Abstract– The oxygen fugacities recorded in the nakhlites Nakhla, Yamato‐000593 (Y‐000593), Lafayette, and NWA998 were studied by applying the Fe,Ti‐oxide oxybarometer. Oxygen fugacities obtained cluster closely around the FMQ (Fayalite–Magnetite–Quartz) buffer (NWA998 = FMQ ? 0.8; Y‐000593 = FMQ ? 0.7; Nakhla = FMQ; Lafayette = FMQ + 0.1). The corresponding equilibration temperatures are 810 °C for Nakhla and Y‐000593, 780 °C for Lafayette and 710 °C for NWA998. All nakhlites record oxygen fugacities significantly higher and with a tighter range than those determined for Martian basalts, i.e., shergottites whose oxygen fugacities vary from FMQ ? 1 to FMQ ? 4. It has been known for some time that nakhlites are different from other Martian meteorites in chemistry, mineralogy, and crystallization age. The present study adds oxygen fugacity to this list of differences. The comparatively large variation in fO2 recorded by shergottites was interpreted by Herd et al. (2002) as reflecting variable degrees of contamination with crustal fluids that would also carry a light rare earth element (REE)‐enriched component. The high oxygen fugacities and the large light REE enrichment of nakhlites fit qualitatively in this model. In detail, however, it is found that the inferred contaminating phase in nakhlites must have been different from those in shergottites. This is supported by unique 182W/184W and 142Nd/144Nd ratios in nakhlites, which are distinct from other Martian meteorites. It is likely that the differences in fO2 between nakhlites and other Martian meteorites were established very early in the history of Mars. Parental trace element rich and trace element poor regions (reservoirs) of Mars mantle ( Brandon et al. 2000 ) must have been kept isolated throughout Martian history. Our results further show significant differences in closure temperature among the different nakhlites. The observed range in equilibration temperatures together with similar fO2 values is attributable to crystallization of nakhlites in the same cumulate pile or lava layer at different burial depths from 0.5 to 30 m below the Martian surface in agreement with Mikouchi et al. (2003) and is further confirmed by similar crystallization ages of about 1.3 Ga ago (e.g., Misawa et al. 2003 ). 相似文献
83.
Petrology and geochemistry of greywackes from Goa-Dharwar sector,western Dharwar Craton: Implications for volcanoclastic origin 总被引:1,自引:0,他引:1
T. C. Devaraju T. L. Sudhakara R. J. Kaukonen R. P. Viljoen T. T. Alapieti S. A. Ahmed S. Sivakumar 《Journal of the Geological Society of India》2010,75(3):465-487
Late Archaean Supracrustals of the Goa-Dharwar sector (GDS) are composed of a thick sequence of greywacke sequence with narrow
intercalations of quartzite, BIF and carbonates. Mafic volcanics occupy the base of the sequence. The greywackes are predominantly
tuffacious containing chlorite-sericite and hornblende. Arkosic variations containing biotite dominate the western part of
the sector. Fine-grained variations occur as isolated narrow lenses within other types of greywackes. The conglomeratic greywackes
are localized along the western and the eastern margins of the sector. All of the greywackes are all typically immature containing
coarser clasts of mostly plagioclase (18–23%) and quartz (32–34%). Lithic fragments of felsic volcanic rocks are common. The
matrix is dominated by mafic material. Biotite and amphibole are related to metamorphic recrystallization. Chlorite, sericite,
epidote, carbonate and chert are products of the interplay of diagenesis and low-grade metamorphism. Fe-Ti oxide, sphene,
apatite and zircon are usual accessories. But for slight enrichment in K2O, the major element chemistry of the GDS greywackes is similar to the chemistry of Late Archaean greywackes. They also compare
in respect of V, Co, Hf contents, K2O/Na2O, SiO2/Al2O3, Na2O/Al2O3, Ba/Rb, Th/U, La/Th, Sm/Nd ratios, steep REE patterns with distinct LREE enrichment and HREE depletion. The GDS greywackes
however are distinctly enriched in Rb, Ba, Sr, Th, U, Cu, Zr, Ce/Ce* and depleted in Cr, Ni, and Zn. The conglomeritic and
biotite bearing verities contain considerable proportions of clasts derived from the basement tonalitic/granitic terrain.
The common tuffacious greywackes containing hornblende and biotite-sericite however include only volcanic clasts and bear
evidence of derivation from submarine weathering of predominantly felsic volcanics erupted on a large scale to form a magmatic
arc in the later stages of geosynclinal deposition. Geochemical data suggest that the GDS greywackes were laid down in progressively
changing basin geometry from a passive to active continental margin and island arc setting. 相似文献
84.
Ahmed Murad 《中国地球化学学报》2010,29(2):152-156
The stable isotopes of oxygen and hydrogen have been implemented to assess the recharge mechanisms in an area in the UAE bounded to the northwestern part of the Gulf of Oman and the southeastern part of the Arabian Gulf. The conversion of stable isotopes to deuterium excess was utilized as a supportive tool to understand the process of groundwater recharge. The concluding results of this study showed that the origin of moisture is the Mediterranean Sea. The precipitation is the main source of recharge, in which the precipitation having undergone evaporation before recharge occurs. The comparison between regression line for data collected in 1996 and regression line for samples collected in 2006 suggests that the precipitation water which recharged the groundwater, was diluted with groundwater and this dilution is observed from decreasing of the deuterium excess of collected groundwater samples with increasing isotopes of oxygen. The dilution of groundwater with the recharge water suggests modern-day recharge as it is seen from high deuterium excess that exceeded the deuterium excess of LMWL and was close to MMWL. 相似文献
85.
Franziska D.H. Wilke Patrick J. O'Brien Uwe Altenberger Matthias Konrad-Schmolke M. Ahmed Khan 《Lithos》2010,114(1-2):70-85
Metabasites were sampled from rock series of the subducted margin of the Indian Plate, the so-called Higher Himalayan Crystalline, in the Upper Kaghan Valley, Pakistan. These vary from corona dolerites, cropping out around Saif-ul-Muluk in the south, to coesite–eclogite close to the suture zone against rocks of the Kohistan arc in the north. Bulk rock major- and trace- element chemistry reveals essentially a single protolith as the source for five different eclogite types, which differ in fabric, modal mineralogy as well as in mineral chemistry. The study of newly-collected samples reveals coesite (confirmed by in situ Raman spectroscopy) in both garnet and omphacite. All eclogites show growth of amphiboles during exhumation. Within some coesite-bearing eclogites the presence of glaucophane cores to barroisite is noted whereas in most samples porphyroblastic sodic–calcic amphiboles are rimmed by more aluminous calcic amphibole (pargasite, tschermakite, and edenite). Eclogite facies rutile is replaced by ilmenite which itself is commonly surrounded by titanite. In addition, some eclogite bodies show leucocratic segregations containing phengite, quartz, zoisite and/or kyanite. The important implication is that the complex exhumation path shows stages of initial cooling during decompression (formation of glaucophane) followed by reheating: a very similar situation to that reported for the coesite-bearing eclogite series of the Tso Morari massif, India, 450 km to the south-east. 相似文献
86.
The particulate nature of granular soils can be accurately simulated at a microscale level. However, due to the huge spatial extent of geotechnical systems, a model fully constructed at such a scale is almost impossible with current computing technologies. Hence, continuum-based approaches are considered as the practical scale for modeling the majority of problems. Combining both scales enables benefiting from the advantages of both techniques while trying to overcome their drawbacks. Although a significant number of publications have addressed coupling both scales, only a few provide information regarding implementing the proposed procedures. In this study, an efficient co-simulation framework for conducting multiscale analysis is introduced. The framework is based on integrating existing continuum and micromechanical modeling software packages and therefore benefitting from already existing codes. A computational simulation of a rigid pile in contact with granular soil demonstrating the capabilities of such technique is presented. The near-field zone surrounding the pile is modeled using DEM whereas FEM is utilized to model far-field zones that are not affected by the presence of the pile. Results of conducted simulations resemble those obtained from experimental results. The proposed approach appears to be a very effective and promising tool to model boundary value problems of geotechnical systems. 相似文献
87.
Numerical modeling of the Rideau Valley Watershed 总被引:1,自引:0,他引:1
Ferdous Ahmed 《Natural Hazards》2010,55(1):63-84
Using the Mike11 modeling system by the Danish Hydraulic Institute, a detailed model of the Rideau Valley Watershed was constructed.
It includes 532 km of rivers and lakes, 106 basins, 122 bridges and culverts, and 20 water control structures. The model was
calibrated using measured streamflow data for a time period of 5 years; additional 5 years of data was used for validation.
Various methods, both qualitative and quantitative, were used to evaluate the model performance. It was found that the model
can simulate the hydrological response with a reasonable to high degree of accuracy. This model is now being used for various
watershed management purposes, including flood forecasting, dam safety assessment, quantification of wetland functions, and
derivation of design flows. 相似文献
88.
Hydrochemistry and Classification of Groundwater Resources of Ishwardi Municipal Area,Pabna District,Bangladesh 总被引:2,自引:0,他引:2
Golzar Hossain M. Farhad Howladar Lutfun Nessa Syed Samsuddin Ahmed Chowdhury Quamruzzaman 《Geotechnical and Geological Engineering》2010,28(5):671-679
The chemical property of groundwater depends largely on the mineralogical composition of the rocks through which the water
has moved and the rate of movement and these characteristics of surface water depend on organic and inorganic reactions, industrial
effluents, rainfall and temperature etc. The underground water tends to contain more dissolved materials than those in surface
water because of their more intimate and longer contact with organic materials of soil and rock particles. The groundwater
of the studied area is dominant of alkaline earth’s (Ca2+ and Mg2+) and weak acids (HCO3
−) which may be classified as Magnesium-Bicarbonate and Calcium Carbonate types. Genetically, the groundwater of the area belongs
to both “Normal Chloride” “Normal Sulphate” and “Normal Carbonate” to “Super Carbonate” group. Based on EC, SAR and RC, the
groundwater of the area varies from good–excellent quality for irrigation purposes with low alkali hazard and medium salinity
hazard. 相似文献
89.
Modelling of paleo-saltwater intrusion in the northern part of the Nubian Aquifer System, Northeast Africa 总被引:2,自引:2,他引:0
A numerical groundwater model of the Nubian Aquifer System was established to prove the influence of rising seawater levels on the groundwater salinity in northern Egypt over the last 140,000 years. In addition, the impact of a groundwater recharge scenario for these 140,000 years, involving climatic change, on the saltwater/freshwater interface was investigated. Saltwater intrusion induced by rising water levels of the Mediterranean Sea led to salinisation from the Mediterranean Sea to the Qattara depression. This modeling approach was supported by a density-driven model setup and calculation. The modelled saltwater/freshwater interfaces partially fitted the observed ones, especially in the southern half of the Qattara depression. In other parts of the northern Nubian Aquifer System, the ingression of salt water was modelled adequately, but in the west, small regions of the measured interface were not. The development in the Qattara depression (Egypt) and Sirte basin (Libya) were investigated in more detail. The different behaviour in the Sirte basin may be due to high evapotranspiration rates in some former periods, salt solutions from the pre-Quaternary layers or saltwater infiltration from sabkha-like recent salt-bearing sediments. 相似文献
90.
Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon 总被引:4,自引:4,他引:0
Y. B. Onundi M.Sc. A. A. Mamun Ph.D. M. F. Al Khatib Ph.D. Y. M. Ahmed M.Sc. 《International Journal of Environmental Science and Technology》2010,7(4):751-758
Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb2+ > Cu2+ > Ni2+. Langmuir model had higher R2 values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals. 相似文献